Answer Save. rihu27 rihu27 Answer: down the group the stability of metellic carbonates imcreass. Explanation: New questions in Chemistry. All the alkaline earth metals form carbonates (MCO 3). 2 Answers. Nitrates of both group 1 and group 2 metals are soluble in water. I cannot wrap my head around this. I am a metal and placed above iron in the activity series. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. A common misconception is that decrease in polarisation of the carbonate ion due to decreased charge density results in thermal stability decreasing down the group, rather than the reverse. The solubility of carbonates in water decreases as the atomic number of the metal ion increases. As we move down group 1 and group 2, the thermal stability of nitrate increases. Top Be. Down the Group the size of metal cation increases, hence charge density and polarising power decreases. All these carbonates decompose on heating to give CO 2 and metal oxide. 2012-08-13 15:58:41. All the Group 2 carbonates and their resulting oxides exist as white solids. The Stability of Group 1 carbonates, M 2 CO 3. MCO 3(s) → MO (s) + CO 2(g) Where M is a Group II element. Li to Na. Why?Consider the thermochemical cycle for the loss of CO2 from the carbonate. The term "thermal decomposition" describes splitting up a compound by heating it. Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding When metal carbonates are heated, they break down to … Solution for group 1 elements with that of group 2 on the basis of the following:… The carbonates and nitrates of group 2 elements carbonates become more thermally stable as you go down the Group. * Thermal stability of group-1 and group-2 carbonates (also of bicarbonates) increases down the group as the polarizing power of the metal ion decreases. Since electropositive character increases from Li to Cs All carbonates and bicarbonate are water soluble and their solubility increases from Li to Cs CHEMICAL PROPERTIES Alkalimetals are highly reactive due to low ionization energy. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Click to see full answer Beside this, how does the thermal stability of alkaline earth metal carbonates vary down the group explain? It describes and explains how the thermal stability of the compounds changes as you go down the Group. Top Answer. Alkali Earth Metals Group 1. 6. Therefore the thermal decomposition temperature is lower or the salt is thermally less stable to heat. I undergo less corrosioncompared to iron. It describes and explains how the thermal stability of the compounds changes as you go down the Group. (i) All the alkaline earth metals form carbonates (MCO 3). The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. 18. But, experimentally, order is reverse. This means that the enthalpy change from the carbonate to the oxide becomes more negative so more heat is needed to decompose it. It describes and explains how the thermal stability of the compounds changes as you go down the Group. 1 decade ago. Thermal decomposition is the term given to splitting up a compound by heating it. Beryllium carbonate is unstable and can be kept only in the atmosphere of CO2. Ensure you provide a clear explanation for the thermal stability of Group 2 carbonates. Group 2 Oxides & Hydroxides w/ Water & Dilute Acid (6:58) Group 2 Salts - Solubility & Tests (7:27) Thermal Stability of Group 1/2 Carbonates (8:19) All these carbonates decompose on heating to give CO 2 and metal oxide. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. solubility stability alkali-metals. Group 1 compounds tend to be more thermally stable than group 2 compounds because the cation has a smaller charge and a larger ionic radius, and so a lower polarising power. Eight resources on the thermal decomposition of the group 1 and 2 nitrates and carbonates. * Due to same reason, carbonates of group-1 are more stable than those of group-2. For Alkaline Earth metals Group 2. Bottom Ba. The same occurs in group 1. Solubility of Carbonates INCREASES(opposite of group 2) from top to bottom. The thermal stability of Group II carbonates increases as we descend the group. Compounds of group 1 are generally stable to heat and usually simply melt. Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. Asked by Wiki User. If "X" represents any one of the elements, the following describes this decomposition: XC O3 (s)→XO(s)+C O2 (g) Down the group, the carbonates require more heating to decompose. To test what you've learned from this lesson- Answer to question 23 the calcium ion has a larger charge (2+) thatn the potassium ion (1+). Explaining Thermal Decomposition Temperature Trend for Group 2 Metal Salts. what is the thermal stability of group 1 carbonates? So, solubility should decrease from Li to Cs. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. The thermal stability with respect to loss of CO 2 decreases down the group. Exceptions are the nitrate and hydrogen carbonate: heat. so, the correct order of thermal stability of given carbonates is: BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Be, Mg and Ca present in second group and K present in the first group. Beryllium carbonate decomposing most easily. Carbonate Structure. However, carbonate of lithium, when heated, decomposes to form lithium oxide. It means the stability increases from M g C O 3 to B a C O 3 . Thermal decomposition is the term given to splitting up a compound by heating it. Wiki User Answered . Solubility. From Li to Cs, thermal stability of carbonates increases. The Facts. Upon heating, carbonates decompose into oxide and carbon dioxide; The thermal stability of group-1 and group-2 carbonates increase down the group. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. A smaller 2+ ion has more charge packed into a smaller volume than a larger 2+ ion (greater charge density).. All the carbonates decompose on heating to give carbon dioxide and the oxide. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. In all cases, for a particular set of e.g. From Li to Cs, due to larger ion size, hydration enthalpy decreases. The first resource is a differentiated worksheet with the questions designed around the style of AQA, Edexcel and OCR exam papers and test students on every aspect of the topic including the reactions, observations, trends, theory of charge density/polarisation and finishes with a few questions … 2 NaNO3 (s) => 2 NaNO2 (s) + O2 (g) heat. The carbonate ion has a big ionic radius so it is easily polarized by a small, highly charged cation. Finally we can explain the thermal stability trend for Group 2. Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. Add your answer and earn points. The thermal stability … It consists of a carbon atom surrounded by three oxygen atom in a trigonal planar arrangement. Whereas bicarbonates give carbonate, water and carbon dioxide. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. share | improve this question | follow | edited Jul 20 '18 at 2:44. For example, Li2CO3 +heat -> Li ­2 O +CO2 MgCO3 +Heat -> MgO +CO2 Na2CO3 +heat -> no effect. Beryllium carbonate is unstable and can be kept only in the atmosphere of CO2. All the carbonates decompose on heating to give carbon dioxide and the oxide. The effect of heat on the Group 2 carbonates. The ones lower down have to be heated more strongly than those at the top before they will decompose. 2 NaHCO3 (s) => Na2CO3 (s) + H2) (g) + CO2 (g) Also, lithium carbonate is unstable … The solubility of carbonates in water decreases as the atomic number of the metal ion increases. ΔH r is the enthalpy of reaction for the conversion of the carbonate ion into the oxide ion and CO 2. Carbonates of metal: Thermal stability The carbonates of alkali metals except lithium carbonate are stable to heat. Group 1 or Group 2 compounds, the thermal stability increases down the group as the ionic radius of the cation increases, and its polarising power decreases. * … Thermal stability of group 2 carbonates? Thermal decomposition is the term given to splitting up a compound by heating it. Solubility of Carbonates and Sulphates DECREASES from top to bottom. Solubility of Hydroxides and Flourides INCREASES from top to bottom. Relevance. Thermal stability increases down the group because the size of the cation (positive ion) increases, so the lattice energy of the carbonate decreases, but the lattice energy of the oxide decreases faster. All of these carbonates are white solids, and the oxides that are produced are also white solids. Favourite answer. So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . The carbonates of alkali metals are stable towards heat. MacNoosa. The carbonates of group-2 metals and that of lithium decompose on heating, forming an oxide and carbon dioxide . Small highly charged positive ions distort the electron cloud of the anion. See Answer. Gaurang Tandon. As we go down the group, the carbonates have to be heated more strongly before they will decompose. 0 0 1. (ii) Carbonates. 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